Cromatografia gasosa bidimensional

Zini, Claudia Alcaraz

Palavras-chave: Comprehensive two-dimensional gas chromatography, heartcut twodimensional gas chromatography.

Resumo: This article presents an overview of two-dimensional gas chromatography, pointing to similarities and differences between heartcut (GC-GC) and comprehensive two-dimensional gas chromatography (GC×GC). A simplified approach of the history of two-dimensional gas chromatography, its theoretical basis and issues related to instrumentation, columns sets, modulators and detectors are presented. GC×GC has been regarded as a convenient technique for complex matrices, such as petrochemicals, food and beverage, flavour and fragrance, environmental samples, forensic samples, etc. A comparison of both two-dimensional techniques shows that GC×GC provides shorter analysis times, higher peak capacity, sensitivity and chromatographic structure, allowing a deeper investigation of the complexity of investigated matrices, especially when associated with time-of-flight mass spectrometry.


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