Aspectos prácticos de la ionización con electrones en la obtención de espectros de masas y su interpretación
Stashenko, Elena E.; Martínez, Jairo R.
Palavras-chave: Espectrometría de masas, ionización por electrones, isómeros.
Resumo: Se describen algunos aspectos prácticos de uno de los métodos más usados, ionización con electrones, para el análisis de compuestos volatilizables y termoestables. Este método encuentra gran aplicación en la técnica de cromatografía de gases acoplada a la espectrometría de masas. Se discuten algunos detalles particulares para la interpretación de los espectros de masas obtenidos por ionización con electrones.
Referências Bibliográficas
1. J.J. Thomson. Rays of positive electricity and their applications to chemical analysis. Logmaus, 1913.
2. A.L. Burlingame, S.A. Carr. Mass spectrometry in the biological sciences. Humana Press, Totowa, NJ, 1996, 570 pp.
3. A.L. Burlingame. Mass spectrometry: modified proteins and glycoconjugates. Gulf Professional Publishing, Amsterdam, 2005, 432 pp.
4. B. Seliger Larsen, C.N. McEwen. Mass spectrometry of biological materials. CRC Press, Boca Raton, FL,1998, 469 pp.
5. D.M. Desiderio. Mass spectrometry of peptides. CRC Press, Boca Raton, FL, 1991, 421pp.
6. D.M. Desiderio. Mass spectrometry: clinical and biomedical applications. Springer, Heidelberg, 1993, 368 pp.
7. G. Siuzdak. Mass spectrometry for biotechnology. Academic Press, New York, 1996, 161 pp.
8. J.N. Housby. Mass spectrometry and genomic analysis. Springer, Heidelberg, 2001, 149p.
9. T.R. Ashe, K.V. Wood, ASTM Committee E-14 on Mass Spectrometry. Novel techniques in fossil fuel mass spectrometry. ASTM International, West Conshohocken, PA, 1989, 202 pp.
10. J.R. de Laeter. Applications of inorganic mass spectrometry. Wiley, New York, 2001, 474pp.
11. R.W. Morrow, J.S. Crain. Applications of inductively coupled plasma-mass spectrometry to radionuclide determinations. ASTM International, West Conshohocken, PA, 1995.
12. T.R. Ashe, K.V. Wood, ASTM Committee E-14 on Mass Spectrometry. Novel techniques in fossil fuel mass spectrometry. ASTM International, West Conshohocken, PA, 1989, 202 pp.
13. T.W. Boutton, S. Yamasaki. Mass spectrometry of soils. Marcel Dekker, New York, 1996, 517 pp.
14. D.C. Duckworth, D.H. Smith. Inorganic mass spectrometry: fundamentals and applications. Marcel Dekker, Inc. New York, 2000, 512 pp.
15. J.R. Chapman. Practical organic mass spectrometry: a guide for chemical and biochemical analysis. John Wiley and Sons, New York, 1995, 338 pp.
16. R.A.W. Johnstone, M.E. Rose. Mass spectrometry for chemists and biochemists. Cambridge University Press, Cambridge, 1996, 501 pp.
17. P. Snyder. Biochemical and biotechnological applications of electrospray ionization mass spectrometry. American Chemical Society, Washington, 1995, 601 pp.
18. J.R. Majer. The mass spectrometer. Wykeham Publications, Londres, 1977, 159 pp.
19. P.H. Dawson. Quadrupole mass spectrometry and its applications. Springer, Heidelberg, 1995, 349 pp.
20. R. March, J.F.J. Todd. Practical Aspects of Ion Trap Mass Spectrometry: Ion trap instrumentation. CRC Press, Boca Raton, FL, 1995, 352p.
21. R. J. Cotter. Time-of-flight mass spectrometry. American Chemical Society, Washington, 1994, 233 pp.
22. R.J. Cotter. Time-of-flight mass spectrometry: instrumentation and applications in biological research. American Chemical Society, Washington, 1997, 326 pp.
23. J. Ramasastry. Mass spectrometry; theory and applications. Plenum Press, New York, 1966, 225 pp.
24. J.T. Watson, O.D. Sparkman. Introduction to Mass Spectrometry: Instrumentation, Applications, and Strategies for Data Interpretation. Wiley, New York, 2007, 862 pp.
25. J.H. Gross. Mass Spectrometry - A Textbook. Springer-Verlag Berlin, Heidelberg 2002, 536 pp.
26. F.W. McLafferty. Interpretation of Mass Spectra. University Science Books, Mill Valley, CA, 1993, 371 pp.
27. K. Downard. Mass spectrometry: a foundation course. Royal Society of Chemistry, Oxford, 2004, 210 pp.
28. E. de Hoffmann, V. Stroobant. Mass spectrometry: principles and applications. Wiley-Interscience, New York, 2007, 489 pp.
29. C. Dass. Fundamentals of Contemporary Mass Spectrometry. Wiley-Interscience, New York, 2007, 608 pp.
30. M.L. Gross, R.M. Caprioli. The Encyclopedia of Mass Spectrometry, Ten-Volume Set, Elsevier, Amsterdam, 2006.
31. A. Maccoll. Mass spectrometry. Butterworths, Londres, 1975, 365 pp.
32. C.A. McDowell. Mass spectrometry. R. E. Krieger Pub. Co., Huntington, NY, 1979, 639 pp.
33. D. Price, J.F.J. Todd. Dynamic mass spectrometry. Heyden, Londres, 1981, 322 pp.
34. C. Merritt, C.N. McEwen. Mass spectrometry. CRC Press, Boca Raton, FL, 1980, 304 pp.
35. J.T. Watson. Introduction to mass spectrometry. Lippincott-Raven, Philadelphia, PA, 1997, 496 pp.
36. J. Barker, D.J. Ando, R. Davis. Mass spectrometry. John Wiley and Sons, New York, 1999, 509 pp.
37. C.A. Schalley. Modern mass spectrometry. Springer, Heidelberg, 2003, 317 pp.
38. C.G. Herbert, R.A. Walker. Mass spectrometry basics. CRC Press, Boca Raton, FL, 2003, 474 pp.
39. Revistas especializadas en la espectrometría de masas: European Journal of Mass Spectrometry (www.impublications.com/journal/ejms) International Journal of Mass Spectrometry (https://www.elsevier.com/wps/find/journaldescription. cws_home/500847/description#description) Journal of the American Society for Mass Spectrometry (www.elsevier.com/wps/find/journaldescription.cws_h ome/505727/description#description) Journal of Mass Spectrometry (www3.interscience.wiley.com/journal/117935721/gro uphome/home.html) Journal of the Mass Spectrometry Society of Japan (www.jstage.jst.go.jp/browse/massspec) Mass Spectrometry Bulletin (www.rsc.org/Publishing/CurrentAwareness/msb/index.asp) Mass Spectrometry Reviews (www3.interscience.wiley.com/journal/49879/home) Rapid Communications in Mass Spectrometry (www3.interscience.wiley.com/journal/4849/home)
40. Algunas revistas de química analítica e instrumental, que publican artículos en los cuales se emplea la espectrometría de masas: Analytical Chemistry (pubs.acs.org/journal/ancham) Analytical and Bioanalytical Chemistry (www.springer.com/chemistry/analytical/journal/216) Analytica Chimica Acta (www.elsevier.com/wps/find/journaldescription.cws_h ome/502681/description#description) Critical Reviews in Analytical Chemistry (www.informaworld.com/smpp/title~content=t713400837) Fresenius’ Journal of Analytical Chemistry (www.springerlink.com/content/110258/) Journal of Analytical Chemistry (www.springerlink.com/content/106287/) International Journal of Environmental Analytical Chemistry (www.tandf.co.uk/journals/titles/03067319.html) TrAC - Trends in Analytical Chemistry (www.elsevier.com/wps/find/journaldescription.cws_h ome/502695/description#description) The Analyst Royal Society of Chemistry (www.rsc.org/Publishing/Journals/an/index.asp)
41. Algunas revistas especializadas en ciencias de separación, que incluyen artículos donde se usa la espectrometría de masas: Journal of Separation Science (www3.interscience.wiley.com/journal/117935715/gro uphome/home.html) Journal of Chromatography A y B (www.elsevier.com/wps/find/journaldescription.cws_h ome/502688/description#description) Journal of Chromatographic Science (www.j-chrom-sci.com/) Chromatographia (www.chromatographia.de) Scientia Chromatographica (www.scientiachromatographica.com)
42. W.M.A. Niessen (Ed.) Current practice of gas chromatography-mass spectrometry. Marcel Dekker Inc., New York, 2001, 528 pp.
43. W.M.A. Niessen (Ed.) Liquid chromatography-mass spectrometry. Global View Publishing, Pittsburgh, PA, 1999, 276 pp.
44. R. Willoughby, E. Sheehan, S. Mitrovich. A global view of LC/MS. Global View Publishing, Pittsburg, PA, 2002, 554 pp.
45. M. Claude, D. Thiebaut (Eds). Practical supercritical fluid chromatography and extraction. Harwood Acad. Publishing, Amsterdam, 1999, 161 pp.
46. A.G. Harrison. Chemical ionization mass spectrometry. CRC Press, Boca Raton, FL, 1983, 156 pp.
47. D.P. Stevenson. Disc. Faraday Soc., 10, 35 (1951).
48. H.E. Audier. Org. Mass Spectrom., 2, 280 (1969).
49. A. G. Harrison, C. D. Finney, J. A. Sherk. Org. Mass Spectrom. 5, 1313 (1971).
50. E.E. Stashenko, J.R. Martínez. Scientia Chromatographica, 1(3), 29 (2009).
51. H.M. Rosenshtock, H.B. Wallenstein, A. Warhaftig, H. Eyring. Proc. Natl. Acad. Sci USA, 38, 667 (1952).
52. E. Solano, E.E. Stashenko, J.R. Martínez, U. Mora, V.V. Kouznetsov. J. Mass Spectrom., 42, 1496 (2007).
53. E. Solano, E.E. Stashenko, J.R. Martínez, U. Mora, V.V. Kouznetsov. J. Mol Struc-Theochem, 769(1-3) 83 (2006)