http://dx.doi.org/10.4322/sc.2011.008

 

Fibras altamente robustas de microextração em fase sólida e recobrimento via reação sol-gel

Carasek, Eduardo; Martendal, Edmar; Budziak, Dilma

Palavras-chave: Microextração em fase sólida, suporte metálico, Ni-Ti, cromatografia, técnicas de preparação de amostras.

Resumo: O aperfeiçoamento de técnicas de preparação de amostras baseadas em sorção e/ou o desenvolvimento de novos materiais é extremamente importante para ampliar sua aplicabilidade, eficiência e robustez. A fragilidade da sílica fundida e a necessidade de suportes robustos para microextração em fase sólida (SPME), bem como uma eficiente interação entre o recobrimento extrator e o suporte, têm levado ao desenvolvimento e aplicação de novos materiais. Neste artigo, será discutido o uso de fios metálicos na confecção de fibras altamente robustas de SPME. Em especial, será destacado o uso da liga de NiTi recoberta com ZrO2 por eletrodeposição, a qual será avaliada como suporte e sorvente extrator para SPME, bem como substrato para reações sol-gel com poli-dimetil-siloxano (PDMS) e poli-etilenoglicol (PEG).


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