http://dx.doi.org/10.4322/sc.2014.012

 

Development of a new system of cold fiber solid phase microextraction

Menezes, Helvécio C.; Cardeal, Zenilda de L.

Palavras-chave: CF-SPME, gas chromatography mass spectrometry, Volatile Organic Compound.

ResumoThis paper presents a description and application of a system of cold fiber solid phase microextraction. The system uses liquid nitrogen transferred by copper tubes to the outside of the SPME fiber. The system is simple, cheap and allows portability. Applications are described for environmental and food analysis.


Referências Bibliográficas

1. Demeestere K, Dewulf J, Witte B, Langenhove H van. Sample preparation for the analysis of volatile organic compounds in air and water matrices. Journal of Chromatography A 2007; 1153(1-2):130- 144. PMid:17258752. http://dx.doi.org/10.1016/j. chroma.2007.01.012
2. D.ettmer K, Engewald W. Ambient air analysis of volatile organic compounds using adsorptive enrichment. Chromatographia 2003; 57(1):S339-S347. http://dx.doi.org/10.1007/BF02492126
3. L.ord H, Yu Y, Segal A, Pawliszyn J. Breath analysis and monitoring by membrane extraction with sorbent interface. Analytical Chemistry 2002; 74(21):5650- 5657. PMid:12433101. http://dx.doi.org/10.1021/ ac025863k
4. J.anfelt C, Graesboll R, Lauritsen FR. Characterization and optimization of membrane inlets for a miniature ion trap mass spectrometer operating at a high background pressure of humid air. International Journal of Mass Spectrometry 2008; 276(1):17-23. http://dx.doi.org/10.1016/j.ijms.2008.06.019
5. K.etola RA, Kiuru JT, Tarkiainen V, Kokkonen JT, Räsänen J, Kotiaho T. Detection of volatile organic compounds by temperature-programmed desorption combined with mass spectrometry and fourier transform infrared spectroscopy. Analytica Chimica Acta 2006; 562(2):245-251. http://dx.doi. org/10.1016/j.aca.2006.01.069
6. M.orley M, Pawliszyn J. Membrane extraction with a sorbent interface and gas chromatography for the characterization of ethylene in human breath. IEEE Sensors Journal 2010; 10(1):167-172. http://dx.doi. org/10.1109/JSEN.2009.2035215
7. H.uang RJ, Hoffmann TJ. A denuder–impinger system with in situ derivatization followed by gas chromatography–mass spectrometry for the determination of gaseous iodine-containing halogen species. Journal of Chromatography A 2008; 1210(2):135-141. PMid:18849042. http://dx.doi. org/10.1016/j.chroma.2008.08.003
8. H.ippelein M. Analysing selected VVOCs in indoor air with solid phase microextraction (SPME): a case study. Chemosphere 2006; 65(2):271-277. PMid:16581103. http://dx.doi.org/10.1016/j.chemosphere.2006.02.041
9. S.tashenko EE, Martinez JR. Derivatization and solidphase microextraction. TrAC Trends in Analytical Chemistry 2004; 23(8):553-561. http://dx.doi. org/10.1016/j.trac.2004.06.002
10. Pan L, Pawliszyn J. Derivatization/solid-phase microextraction: new approach to polar analytes. Analytical Chemistry 1997; 69(2):196-205. http:// dx.doi.org/10.1021/ac9606362
11. Z.hang ZY, Pawliszyn J. Quantitative extraction using an internally cooled solid phase microextraction device. Analytical Chemistry 1995; 67(1):34-43. http:// dx.doi.org/10.1021/ac00097a007
12. M.enezes HC, Cardeal ZL. Determination of polycyclic aromatic hydrocarbons from ambient air particulate matter using a cold fiber solid phase microextraction gas chromatography–mass spectrometry method. Journal of Chromatography A 2011; 1218(21):3300- 3305. PMid:21093868. http://dx.doi.org/10.1016/j. chroma.2010.10.105
13. G.hiasvand AR, Hosseinzadeh S, Pawliszyn J. New coldfiber headspace solid-phase microextraction device for quantitative extraction of polycyclic aromatic hydrocarbons in sediment. Journal of Chromatography A 2006; 1124(1-2):35-42. PMid:16714028. http:// dx.doi.org/10.1016/j.chroma.2006.04.088
14. M.enezes HC, Paulo BP, Costa NT, Cardeal ZL. New method to determination of naphthalene in ambient air using cold fiber-solid phase microextraction and gas chromatography–mass spectrometry. Microchemical Journal 2013; 109:93-97. http://dx.doi. org/10.1016/j.microc.2012.03.031
15. A.morim LCA, Carneiro JP, Cardeal ZL. An optimized method for determination of benzene in exhaled air by gas chromatography–mass spectrometry using solid phase microextraction as a sampling technique. Journal of Chromatography B 2008; 865(1-2):141- 146. PMid:18346945. http://dx.doi.org/10.1016/j. jchromb.2008.02.023
16. M.oreira MA, Amorim LCA, Cardeal ZL. Analysis of migration to the dibutylphthalate for food simulants in plastic containers using fiber cooled and gas chromatography mass spectrometry. In: 36th International Symposium on Capillary Chromatography; 2012; Riva del Garda.
17. C.ooperation on International Traceability in Analytical Chemistry – CITAC, Eurachem. Guide to Quality in Analytical Chemistry: An Aid to Accreditation. CITAC, Eurachem; 2002 [cited 2013 June 20]. Available from: http://www.eurachem.org/images/stories/Guides/ pdf/CITAC_EURACHEM_GUIDE.pdf.