http://dx.doi.org/10.4322/sc.2016.025

 

Basic principles and applications of liquid phase microextraction techniques

Nerin, Cristina

Palavras-chave: Microextraction, trace analysis, LPME, micro, devices.

Resumo: The main liquid phase techniques for sample preparation have been explored. Among them, two phases devices such as single drop microextraction (SDME) and hollow fibre liquid phase microextraction (HFLPME), either in head space or total immersion modes, both static and dynamic ones; dispersive liquid phase microextraction (DLPME) and microextraction by demixture have been explained. Also three liquid phases using the donor-acceptor interactions, either spontaneous or electro-assisted using a membrane, were reviewed and explained. Several applications as example of each technique will illustrate the advantages and drawbacks of each technique


Referências Bibliográficas

[1] Michael A. Jeannot and Frederick F. Cantwell. Solvent Microextraction into a Single Drop. Anal. Chem., 1996, 68 (13), pp 2236-2240.
[2] R. Batlle, C. Nerín. Application of single drop microextraction to the determination of dialkyl phthalate esters in food simulants. Journal of Chromatography A 1045, 29-35, 2004.
[3] J Romero, P López, C Rubio, R Batlle, C Nerín. Strategies for single drop microextraction optimization and validation. Application to the detection of potential antimicrobial agents. J. of Chromatography. 1166, 1-2, 28 September 2007, 24-29, 2007.
[4] E. Psillakis, N. Kalogerakis. Developments in single-drop microextraction. Trends in analytical chemistry, vol. 21, no. 1, 2002.
[5] Li Xu, Chanbasha Basheer, Hian Kee Lee. Developments in single-drop microextraction. Journal of Chromatography A, 1152 (2007) 184-192.
[6] F. Ahmadi, Y. Assadi, S.M.R. Milani Hosseini, M. Rezaee. Determination of organophosphorus pesticides in water samples by single drop microextraction and gas chromatography-flame photometric detector. Journal of Chromatography A, 1101 (2006) 307-312.
[7] Batlle, R., López, P. Nerín, C. Crescenzi, C. Active single-drop microextraction for the determination of gaseous diisocyanates J. of Chromatography A, 1185, 155-160, 2008.
[8] Gang Shen and Hian Kee Lee. Hollow Fiber-Protected Liquid-Phase Microextraction of Triazine Herbicides. Anal. Chem., 2002, 74 (3), pp 648-654.
[9] A. Rodríguez, S. Pedersen-bjergaard, K. E. Rasmussen, C. Nerín. Selective three phase liquid phase microextraction of acidic compounds from foodstuff simulants. J. of Chromatography A, 1198-1199, 38-440, 2008.
[10] A. Rodríguez-Lafuente, C. Nerín de la Puerta and R. Batlle. Determination of fifteen active compounds released from paraffin-based active packaging in tomato samples via microextraction techniques.Analytical and Bioanalytical Chemistry, 395, 203-211, 2009.
[11] J Salafranca, D Pezo, C Nerín. Assessment of specific migration to aqueous simulants of a new active food packaging containing essential oils by means of an automatic multiple dynamic hollow fiber liquid phase microextraction system. J. of Chromatography A, 1216, 3731-3739, 2009.
[12] Camila Dutra, Davinson Pezo, Maria Teresa de Alvarenga Freire, Cristina Nerín, Felix Guillermo Reyes Reyes. Determination of volatile organic compounds in recycled polyethylene terephthalate and high-density polyethylene by headspace solid phase microextraction gas chromatography mass spectrometry to evaluate the efficiency of recycling processes. Journal of Chromatography A, 1218,1319-1330, 2011.
[13] Rosero-Moreano Milton; Aguirre Mauricio; Pezo Davinson; Taborda Gonzalo; Dussán Carmen And Nerin Cristina. Solventless microextraction techniques for determination of trihalomethanes by gas chromatography in drinking water. Water, Air and Soil Pollution, 223, 2, 667-678, February 2012 – Doi: 10.1007/s11270-011-0891-9, 2012.
[14] Éder Costa Oliveira, Yolanda Echegoyen, Sandra Andrea Cruz, Cristina Nerin. Comparison between Solid Phase Microextraction (SPME) and Hollow Fiber Liquid Phase Microextraction (HFLPME) for determination of extractables from post-consumer recycled PET into food simulants. Talanta 127, 59-67 – DOI:10.1016/j.talanta.2014.03.042 – 2014.
[15] Liliana Correa, Jhon Alex Fiscal, Sandra Ceballos, Alberto de la Ossa, Gonzalo Taborda, Cristina Nerin and Milton Rosero-Moreano. Hollow-fiber solvent bar microextraction with gas chromatography and Electron capture detection determination of disinfection byproducts in water samples. Journal of Separation Science, 2015, 38, 22, 3945–3953, doi:10.1002/jssc.201500324
[16] Jhon Alexander Fiscal Ladino, Sandra Liliana Correa Chacón, Sandra Ceballos Loaiza, Alberto de la Ossa Salcedo, Gonzalo Taborda Ocampo, Cristina Nerin, Milton Rosero-Moreano. Development of a new liquid phase microextraction method with hollow fiber HFSBME for the analysis of the organochlorine compounds in water samples by GC-ECD. Scientia Chromatographica 2014; 6(4), 1-10, doi:10.4322/sc.2014.000
[17] Ali Sarafraz-Yazdi, Amirhassan Amiri. Liquid-phase microextraction. Trends in Analytical Chemistry, Vol. 29, No. 1, 2010.
[18] Pezo, D; Salafranca, J; Nerín, C. Development of an automatic multiple dynamic hollow fiber liquid-phase microextraction procedure for specific migration analysis of new active food packagings containing essential oils. J. of Chromatography A, 1174, 85-94, 2007.
[19] A. Rodríguez; S. Pedersen-Bjergaard; K.E. Rasmussen; C. Neríın. Journal of Chromatography A, 1198–1199 (2008) 38-44.
[20] Mohammad Rezaee, Yaghoub Assadi, Mohammad-Reza Milani Hosseini, Elham Aghaee, Fardin Ahmadia, Sana Berijani. Determination of organic compounds in water using dispersive liquid–liquid microextraction. Journal of Chromatography A, 1116 (2006) 1-9.
[21] C. Nerín, T. Polo, J. Salafranca, J. Cacho. Fast microextraction by demixture and determination of organochlorine pesticides in water. International Journal of Environmental Analytical Chemistry, Vol. 65, 27-35, 1996.
[22] J. Cacho, J. Salafranca, V. Ferreira, C. Nerín. International Journal of Environmental Analytical Chemistry, Vol. 60, 23-32, 1995.